To enchant anything decent, you basically have to Fortify your Intelligence or Enchant skill to superhuman levels via Alchemy or Custom spells.

The Master Enchant trainer also happens to be hostile, just to add insult to injury, so you'll need Calm spells/items or similar in order to purchase training from him. For this reason, there's basically no point making it a Major or Minor skill it's next to impossible to train naturally, and offers pretty much no benefit unless it is at a high level. Enchant levels horribly slowly, to the point that the only efficient way to level it is through training. Having 50 Enchant means items will use 0.6x normal charge, having 100 means they use 0.1x normal charge, and at 110 Enchant skill items use 1 charge maximum per cast. Enchant skill only offers a significant decrease in item charge use at higher levels. Enchant skill is only really worth investing in if you decide to use a lot of Cast When Used items, as the skill level correlates with how much charge an item will use. In a nutshell, without delving too much into the formula: The author of this mage guide breaks down how Enchant skill works in Morrowind. The issue is that Enchant skill in Morrowind is not balanced properly at all, in that it is horribly overpowered, yet horribly difficult to train or use, at the same time. If anyone can explain or clarify what is going on here, that would be appreciated because I feel like I wasted gold training my character's enchant level for absolutely nothing. Is there something wrong with enchanting things on your own now? I don't recall from my Xbox days with Morrowind years ago there ever being an issue with self-enchanting, though this might have something to do with trying to put a constant effect on the amulet (yes I used a golden saint in a grand soul gem).

What is the deal here? Even at level 30 my marksman skill still works much of the time. Still would not work (the console command worked but my character's success rate didn't). Then I got curious and tried using a console command to raise my character's enchant level to 100. Over and over again, Still would not work. So I trained my character's enchant level all the way up to 50 at Tyermaillin's house in Balmora inbetween doing Redoran faction quests and then tried enchanting an exquisite white amulet. I got rather annoyed and frustrated trying over and over again to enchant my own items because enchanters are way too expensive for their own good, even those who are a member of your own faction.

Morrowind items with highest enchant